自然科学版 英文版
自然科学版 英文版
自然科学版 英文版

您目前所在的位置:首页 - 期刊简介 - 详细页面

中南大学学报(英文版)

Journal of Central South University

Vol. 22    No. 8    August 2015

[PDF Download]    [Flash Online]

    

Reduction of lead sulfate to lead sulfide with carbon monoxide
ZHENG Yong-xing(郑永兴), LIU Wei(刘维), QIN Wen-qing(覃文庆), JIAO Fen(焦芬), HAN Jun-wei(韩俊伟), YANG Kang(杨康), LUO Hong-lin(罗虹霖)

School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China

Abstract:In order to decrease the solubility of PbSO4 and enhance lead recovery from PbSO4 bearing wastes, CO was employed as a reductant to transform PbSO4 into PbS. Reaction system was established and reductive thermodynamics of PbSO4 was calculated by software HSC 5.0. The effects of gas concentration, reaction temperature, time and mass of sample on reduction of PbSO4 were examined by thermogravimetry (TG) and XRD. Roasting tests further verify the conclusions of thermodynamic and TG analyses. The results show that increasing temperature in the reasonable range and CO content are favorable for the formation of PbS. The reduction process is controlled by chemical reaction and calculation value of the activation energy is 47.88 kJ/mol.

 

Key words: lead sulfate; reduction; carbon monoxide; lead sulfide; pyrometallurgy

中南大学学报(自然科学版)
  ISSN 1672-7207
CN 43-1426/N
ZDXZAC
中南大学学报(英文版)
  ISSN 2095-2899
CN 43-1516/TB
JCSTFT
版权所有:《中南大学学报(自然科学版、英文版)》编辑部
地 址:湖南省长沙市中南大学 邮编: 410083
电 话: 0731-88879765(中) 88836963(英) 传真: 0731-88877727
电子邮箱:zngdxb@csu.edu.cn 湘ICP备09001153号